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In both these specifications are test methods that are not approved for accept/reject criteria, but that produce data that is useful for process development, shows what really happens during the assembly process, and if tested correctly meets the most stringent of evaluations to modern measurement analysisThese are tests E, F, and G for the J-STD-002 and test F for the J-STD-003 The test protocol detailed in this chapter is designed to change the test status of the wetting balance to one capable of producing accept/reject data, and more importantly, to provide accurate data for process improvements 4222 Definitions of Terms For soldering to occur some obvious fundamentals must be met: 1 The part needs to be fluxed see following definition 2 The part must be solderable see following definition 3.

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and was formed by a lift-off pattern in a PMMA resist) [3]

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There must be sufficient thermal energy to allow wetting to occur typically 35 to 50 C above the Liquidus point of the alloy being used Soldering is defined as a metallurgical joining method using a filler metal (the solder) with a melting point below 842 F (450 C) Soldering relies on wetting for the bond formation, and is defined in the ANSI-JSTD-002 as the ability of a metal to be wetted by molten solder Wetting is defined as the formation of a relatively uniform, smooth, unbroken, and adherent film of solder to a basis metal 4223 The Choice and Impact of Fluxes for Solderability Testing Flux is an integral part of soldering and solderability testing A flux used for solderability testing should never produce false positives or negatives It should demonstrate the true characteristic of the sample being evaluated.

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Some examples are whether it s old, composed of intermetallics, buried under a layer of oxides, contaminated with organics, hiding a poorly wettable basis metal, or showing a clean fresh readily solderable surface 42231 Flux Functions A flux has three main functions:.

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1. To act as chemistry that reduces oxides on a wettable surface. 2. To provide the correct interfacial energy potential between the flux/solder interface and the solder substrate interface. 3. To prevent oxidation from forming during the soldering process and to a lesser extent in the case of liquid fluxes they may protect the surface on the PCB from the extreme temperatures. It may also act as a heat transfer medium. Fluxes are necessary for soldering. While flux-free soldering is possible, in the presence of a reducing gas atmosphere, it is very uncommon. When attempting to check for solderability characteristics without the use of a flux, at best the solder will stick to the sample but will not wet the surface to form a true metallurgical bond.At the other extreme end of the scale are people using fluxes so strong that nothing will ever fail a solderability test. These fluxes do not represent anything used in the assembly industry.A great example of this is the use of the Hot Air Solder Level (HASL) flux for outgoing solderability testing. This type of flux typically uses 5 percent HCl or 5 percent HBr as the active ingredient which, when applied to a surface finish, will reduce any oxide layer present and reactivate any potentially passivated nickel layer and thus always produce a pass result. This is not what is supposed to be used and it does not provide any information pertaining to the actual solderability of the sample being tested because it passes all the time. 42.2.3.2 Fluxes and Evaluation of Solderability. There has been a fundamental change in how solderability is evaluated. The need to demonstrate a year of shelf life has been

replaced with a test for how robust a deposit or plating is The more robust the deposit, the greater the potential shelf life and the ability to survive the complicated higher temperature exposures found in Pb-free assembly When making the choice in terms of solderability testing, it is important that the chosen flux is active enough to overcome finger oils and light surface oxidation and to promote wettingAt the same time, it should not be capable of reducing heavy oxides or wetting to exposed and oxidized intermetallic compounds For many years the use of the R flux for solderability testing was the norm, and it was referenced in that venerable specification MIL STD 202, method 208 The weight consists of 25 percent colophony and 75 percent alcohol The activation level is approximately 0.

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