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Note the very different CARS intensities as well as bandshapes for the various excitation wavelengths of the pump laser (A,, which corresponds to U L of the CARS process as outlined in Sec 3622) which are due to different resonant enhancements Comparing spectrum (k) with (c), for example, shows in addition the very high dynamic range (at least four orders of magnitude) inherent in this type of spectroscopy Analyzing the CARS spectra together with the absorption spectra of several substituted DA crystals, the authors were able to derive important structural as well as electronic properties of this type of crystal For details on resonance CARS studies on various types of diacetylene single crystals we refer to the original literature (Materny and Kiefer, 1992 a-e, 1993; Materny et al, 1992 a-c; Ganz et al, 1993).

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Another, instructive example for resonance CARS in a solid model system has been reported by Leuchs and Kiefer (1993 a) Polarized resonance CARS experiments on the v~ vibration of the permanganate ion doped in a KC104 crystal at low temperature were performed At a temperature of IS K the vibronic structure of the resonant, excited electronic state is well resolved as revealed by a low temperature absorption spectrum of the single crystal (see upper spectrum in Fig 61-24) The experimentally observed absorption spectrum could be simulated in good agreement with the experiment by making use of the time-correlator formulation for the optical absorption in the dipole approximation (Page, 199 I).

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By tuning the pump wavelength (eangular frequency W L ) across the vibronically resolved absorption region, whose main peaks correspond to the v~ progression of the permanganate ion in the excited electronic state, the v~ CARS excitation profile can be obtained as shown in the lower part of Fig 61-24 i n a linear as well as a logarithmic (loglo) vertical scale On the linear scale one can particularly recognize a strong and sharp peak at angular frequency W L < 18050 cm-l, which can be explained by the fact that both intermediate states of the CARS process are in resonance with vibrational v1 states in the excited electronic state (see the CARS energy level diagram in Fig 6.

Totem video player As for multimedia support, GNOME continues to improve its Totem video player, which is based on the GStreamer multimedia framework. Playlists are now integrated into the Totem sidebar, and DVD menus and subtitles are supported. Totem includes increased support for multiple playlist formats, including the standard CML Sharable Playlist Format, QuickTime Metalink playlists, and RealAudio playlists. Application installation and management tools After Ubuntu is installed, you can use the Add/Remove Programs selection from the System Administration menu to install new applications or to remove existing ones you don t want anymore. You can also use the Synaptic package manager to browse all available packages in the Ubuntu repositories, making it easy to find and install the open source applications that do exactly what you need to do. Beyond these features, Ubuntu contains a broad range of open source applications suitable for the desktop. Leading the list are the latest versions of OpenOffice.org (popular office productivity suite), the GIMP (image manipulation software), and Firefox (Web browser). Many of the tools for configuring and setting preferences for the desktop that come with the GNOME project also fit well into the Ubuntu goals of accessibility and ease-of-use. GNOME s Removable Drives and Media Preferences window is set to immediately launch appropriate applications when you insert a CD or DVD, attach an external hard disk, or plug in a camera, printer, or scanner. The Assistive Technology Preferences window enables someone who is visually or physically impaired to use magnifiers and onscreen keyboards. Figure 17-1 shows examples of some of these GNOME tools and applications.

1-24 which has been rotated by 90" from the usual presentation to fit to a horizontal energy scale in order to coincide with the wavenumber scale for absorption and excitation profile) Because of anharmonicity of the v1 vibration and a small but not negligible difference between the wavenumber of the v1 vibration in the ground and excited electronic states the pronounced double resonance feature occurs only at excitation with angular frequency W L around 18050 cm-' However, weaker resonance features can be seen particularly in the log scale CARS excitation profile presentation in the lower part of Fig 61-24 The latter could also be calculated numerically by a theory.

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The statement in Figure 25-24 uses the four most common SQL commands. Table 25-3 shows each command and explains its purpose.

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